Direct coupling of carbenium ions with indoles and anilines for the synthesis of cationic π-conjugated dyes.

نویسندگان

  • Rémi Vanel
  • François-Alexandre Miannay
  • Eric Vauthey
  • Jérôme Lacour
چکیده

A C-C bond forming reaction occurs spontaneously between tris-(2,6-dimethoxyphenyl)carbenium ions and indoles/anilines. The carbocation acts both as an electrophile and an oxidant. Effective cationic π-conjugated dyes are formed resulting in a strong hyper- and bathochromism.

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عنوان ژورنال:
  • Chemical communications

دوره 50 81  شماره 

صفحات  -

تاریخ انتشار 2014